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Demonstration Experiment on Video

Briggs-Rauscher Reaction

Objective: Mechanism of an Oscillating Reaction

Peter Keusch






German version



Chemicals:
hydrogenperoxide 30 %
potassium iodate
malonic acid
manganese(II) sulfate monohydrate
conc. H2SO4
starch, soluble

Apparatus and glass wares:
magnetic stirrer
4 magnetic stirring bars
stirring bar remover
crystallizing dish 140 · 75
3 beakers 1500 mL
3 beakers 500 mL
beaker 150 mL
10 mL measuring pipette (fully graduated 0.1 mL divisions)
pipette bulb
measuring cylinder 500 mL
3 measuring cylinders 250 mL


Hazards and safety precautions:

Iodine is produced. Iodine is toxic - may be fatal if swallowed or inhaled. Harmful by inhalation and through skin absorption. Readily absorbed through skin. Very destructive of mucous membranes and upper respiratory tract, eyes and skin. Severe irritant.
Conc. sulfuric acid is highly toxic. Causes severe burns. May be fatal if swallowed. May cause cancer through inhalation. Very destructive of mucous membranes.
Potassium iodate is harmful if swallowed. May be harmful by inhalation or through skin absorption. Irritant.
Hydrogenperoxide 30 % is toxic, corrosive - can cause serious burns. Eye contact can cause serious injury, possibly blindness. Harmful by inhalation, ingestion and skin contact.







Safety goggles and protective gloves must be worn. The experiment should be performed in a well ventilated room.


Experimental procedure:

The following solutions are prepared in advance:
Solution A:   410 mL of 30% hydrogenperoxide are diluted to 1.0 liter with distilled water in a 1500 mL beaker.
Solution B:   43 g of potassium iodate are dissolved in about 800 mL of dist. water + 4.3 ml of conc. sulfuric acid
in a 1500 mL beaker. The mixture is made up to 1000 mL with dist. water
Solution C:   16 g of malonic acid and 3.4 g of manganese (II) sulfate monohydrate are dissolved in about 500 mL of dist. water in a 1500 mL beaker. 3 g of soluble starch are dissolved in 100 mL of boiling dist. water in a 150 mL beaker. The starch solution is poured into the solution of malonic acid and manganese sulfate. The mixture is diluted with dist. water to 1000 mL.

250 mL of each the solutions A and B are poured into a crystallizing dish. The mixture is stirred vigorously with a magnetic stirrer.


Result:

The initially colorless solution becomes amber almost immediately. Then it suddenly turns blue-black. The blue-black fades to colorless. Thus the color of the solution oscillates between clear, brownish and deep blue.


Briggs-Rausche 1 Briggs-Rausche 2 Briggs-Rausche 3

Video clip
(Download RealPlayer .rm file)


Discussion:
Briggs-Rauscher Oscillating Color Change Reaction


Reference:
  Demonstration Experiment on Video   Belousov-Zhabotinsky-Reaction



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